Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

Literature Information

Publication Date 2008-06-10
DOI 10.1039/B806949B
Impact Factor 6.222
Authors

Shelli R. Waetzig, Jon A. Tunge


View Original

Abstract

This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides.

Related Literature

The mechanism of the Ser-(cis)Ser-Lys catalytic triad of peptide amidases

N. M. F. S. A. Cerqueira, H. Moorthy, P. A. Fernandes, M. J. Ramos

2017-03-30 Paper

DOI: 10.1039/C7CP00277G

Contents list

Front/Back Matter

DOI: 10.1039/C7CP90107K

Optimization of hydrophilic/hydrophobic phase separation in sPEEK membranes by hydrothermal treatments

H. Mendil-Jakani, I. Zamanillo López, V. H. Mareau, L. Gonon

2017-05-22 Paper

DOI: 10.1039/C7CP00087A

Molecular dynamics simulations of the structure and the morphology of graphene/polymer nanocomposites

S. Güryel, M. Walker, P. Geerlings, F. De Proft, M. R. Wilson

2017-04-28 Paper

DOI: 10.1039/C7CP01552F

Preparation and characterization of a calcium–phosphate–silicon coating on a Mg–Zn–Ca alloy via two-step micro-arc oxidation

Jinhe Dou, Yang Chen, Yiming Chi, Huancai Li, Guochao Gu, Chuanzhong Chen

2017-05-19 Paper

DOI: 10.1039/C7CP02672B

Well incorporation of carbon nanodots with silicon nanowire arrays featuring excellent photocatalytic performances

Chia-Yun Chen, Po-Hsuan Hsiao, Ta-Cheng Wei, Ting-Chen Chen, Chien-Hsin Tang

2017-04-24 Paper

DOI: 10.1039/C7CP01674C

Ab initio assessment of Bi1−xRExCuOS (RE = La, Gd, Y, Lu) solid solutions as a semiconductor for photochemical water splitting

Sheikha Lardhi, Antton Curutchet, Luigi Cavallo, Moussab Harb, Tangui Le Bahers

2017-04-12 Paper

DOI: 10.1039/C7CP01684K

Inside front cover

Cover

DOI: 10.1039/C7CP90129A

The effect of K+ cations on the phase transitions, and structural, dielectric and luminescence properties of [cat][K0.5Cr0.5(HCOO)3], where cat is protonated dimethylamine or ethylamine

Maciej Ptak, Anna Gągor, Adam Sieradzki, Bartosz Bondzior, Przemysław Dereń, Aneta Ciupa, M. Trzebiatowska, Mirosław Mączka

2017-04-19 Paper

DOI: 10.1039/C7CP01336A

You might also like

Compound Q&A

Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?

When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...

3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A

How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?

3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...

419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A

How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?

5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...

1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A

What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?

2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...

1206978-15-52-Chloro-4-(difluoro...
Compound Q&A

What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?

3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...

1121-79-53-Chloro-6-methylpyr...
Compound Q&A

Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?

Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...

90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A

Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?

Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...

63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A

What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?

3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...

1261906-29-93-Amino-5-chloropyri...
Compound Q&A

What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?

When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...

1092349-93-36,7-Difluoro-2,3-dih...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.