A molecular wire incorporating a robust hexanuclear platinum cluster
Literature Information
Edmund Leary, Harm Van Zalinge, Simon J. Higgins, Richard J. Nichols, Fabrizia Fabrizi de Biani, Piero Leoni, Lorella Marchetti, Piero Zanello
Reaction of [Pt6(CO)4(PtBu2)4Cl2] with excess HS(CH2)4SH in Et2NH gave highly stable [Pt6(CO)4(PtBu2)4{S(CH2)4SH}2], which adsorbs unchanged onto gold surfaces. This permitted the fabrication and electrical characterisation of gold|molecule|gold junctions involving a well-defined metal carbonyl cluster compound.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














