Isomorphous CoII and MnII materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours

Literature Information

Publication Date 2008-09-22
DOI 10.1039/B811865E
Impact Factor 6.222
Authors

Qin-Xiang Jia, Yan-Qin Wang, Qi Yue, Qing-Lun Wang, En-Qing Gao


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Abstract

Two isomorphous CoII and MnII three-dimensional coordination polymers with tetrazolate-5-carboxylate as magnetic mediator exhibit an unprecedented 3,4-connected self-penetrating net topology; a combination of canted antiferromagnetism and metamagnetism was observed in the CoII compound, whereas the MnII compound shows typical antiferromagnetic behaviors.

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