A total loss of innocence: double ortho-metallation of bis(triphenylphosphano)iminium cation, [N(PPh3)2]+, by tris(η-naphthalene)tantalate(1−)‡
Literature Information
Publication Date
2008-10-01
DOI
10.1039/B811320C
Impact Factor
6.222
Authors
Victor J. Sussman, John E. Ellis
View Original
Abstract
For the first time [N(PPh3)2]+, or [PPN]+, has been shown to undergo an irreversible reaction with a transition metal complex under ambient conditions and affords a product containing a unique structural motif in which two phenyl groups on onePPh3 substituent of [PPN]+ are ortho-metallated, while the third phenyl ring is hydrogenated to provide a tantalum bound 1,3-cyclohexadiene group.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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Recommended Compounds
![9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate structure](https://static.chemtradehub.com/structs/131/1314378-14-7-4316.webp "9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate structure")
9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate
CAS Number:
1314378-14-7
Molecular Formula:
C30H36N2O10
![(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid structure](https://static.chemtradehub.com/structs/218/218608-96-9-f871.webp "(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid structure")
(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid
CAS Number:
218608-96-9
Molecular Formula:
C15H20ClNO4
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