A total loss of innocence: double ortho-metallation of bis(triphenylphosphano)iminium cation, [N(PPh3)2]+, by tris(η-naphthalene)tantalate(1−)‡

Literature Information

Publication Date 2008-10-01
DOI 10.1039/B811320C
Impact Factor 6.222
Authors

Victor J. Sussman, John E. Ellis


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Abstract

For the first time [N(PPh3)2]+, or [PPN]+, has been shown to undergo an irreversible reaction with a transition metal complex under ambient conditions and affords a product containing a unique structural motif in which two phenyl groups on onePPh3 substituent of [PPN]+ are ortho-metallated, while the third phenyl ring is hydrogenated to provide a tantalum bound 1,3-cyclohexadiene group.

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