Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM: Guinness is good for SET-LRP
Literature Information
Publication Date
2013-09-11
DOI
10.1039/C3PY01075A
Impact Factor
5.582
Authors
Christopher Waldron, Qiang Zhang, Zaidong Li, Vasiliki Nikolaou, Gabit Nurumbetov, Jamie Godfrey, Ronan McHale, Gokhan Yilmaz, Rajan K. Randev, Mony Girault, Kayleigh McEwan, David M. Haddleton, Martijn Droesbeke, Alice J. Haddleton, Paul Wilson, Alexandre Simula, Jennifer Collins, Danielle J. Lloyd, James A. Burns, Christopher Summers, Claudia Houben, Athina Anastasaki, Muxiu Li, C. Remzi Becer, Jenny K. Kiviaho, Nuttapol Risangud
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Abstract
The controlled polymerization of N-isopropyl acrylamide (NIPAM) is reported in a range of international beers, wine, ciders and spirits utilizing Cu(0)-mediated living radical polymerization (SET-LRP). Highly active Cu(0) is first formed in situ by the rapid disproportionation of [Cu(I)(Me6-Tren)Br] in the commercial water–alcohol mixtures. Rapid, yet highly controlled, radical polymerization follows (Đ values as low as 1.05) despite the numerous chemicals of diverse functionality present in these solvents e.g. alpha acids, sugars, phenols, terpenoids, flavonoids, tannins, metallo-complexes, anethole etc. The results herein demonstrate the robust nature of the aqueous SET-LRP protocol, underlining its ability to operate efficiently in a wide range of complex chemical environments.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
1,3(2H,4H)-Isoquinolinedione, 7-amino-4,4-dimethyl-
CAS Number:
14576-22-8
Molecular Formula:
C11H12N2O2
![(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure](https://static.chemtradehub.com/structs/250/2505001-54-5-c1e9.webp "(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure")
(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide
CAS Number:
2505001-54-5
Molecular Formula:
C16H20ClN3O4S
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