Separation of a diiminopyridine iron(ii) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization

Literature Information

Publication Date 2008-09-12
DOI 10.1039/B810381J
Impact Factor 6.222
Authors

Antonio Rodríguez-Delgado, Juan Cámpora, A. Marcos Naz, Pilar Palma, Manuel L. Reyes


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Abstract

Separation of a diiminopyridine iron(II) complex into its rac- and meso- diastereoisomers provides for first time the opportunity of observing the enantiomorphic site control competing with the chain-end control mechanism in a non-metallocene catalyst system.

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