Formation of N-bridgehead 1,2,5-thiadiazolium and selenadiazolium rings through an intramolecular cyclisation reaction

Literature Information

Publication Date 2008-09-18
DOI 10.1039/B809987A
Impact Factor 6.222
Authors

Catherine E. Bacon, Dana J. Eisler, Rebecca L. Melen, Jeremy M. Rawson


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Abstract

Treatment of N-lithiopyridylketimide derivatives Li[R(C = N)py] (R = Ph, py) with ECl2 (E = S, Se) affords the fused thiadiazolium and selenadiazolium salts [RC6H4N2E]Cl [1]Cl and [2]Cl containing a bridgehead N atom through intramolecular coordination.

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