Heavier group 2 element-catalysed hydroamination of isocyanates

Literature Information

Publication Date 2008-09-12
DOI 10.1039/B809649J
Impact Factor 6.222
Authors

Anthony G. M. Barrett, Tanya C. Boorman, Mark R. Crimmin, Michael S. Hill, Gabriele Kociok-Köhn, Panayiotis A. Procopiou


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Abstract

The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR2)(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe3, Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe3)2}2] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

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