Deprotonative cadmation of functionalized aromatics
Literature Information
Jean-Martial L’Helgoual’ch, Floris Chevallier, Mitsuhiro Yonehara, Masanobu Uchiyama, Aïcha Derdour, Florence Mongin
This communication describes the deproto-metalation of a large range of aromatics including heterocycles using a newly developed lithium–cadmium base; the reaction proceeds at room temperature with an excellent chemoselectivity and efficiency, and proved to be regioselective in most cases.
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Chemical Communications

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