Enantiomerically purebicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

Literature Information

Publication Date 2008-09-12
DOI 10.1039/B807669C
Impact Factor 6.222
Authors

Tharmalingam Punniyamurthy, Monika Mayr, Alexander S. Dorofeev, Carole J. R. Bataille, Silvia Gosiewska, Bao Nguyen, Andrew R. Cowley, John M. Brown


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Abstract

In situ resolution of the rapidly racemising diphosphine BIPHEP and its relatives with the cationic Rh complex of (S,S)-bicyclonona-2,6-diene permits the asymmetric hydrogenation of dehydroamino esters.

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