Concerted attack of frustrated Lewis acid–base pairs on olefinic double bonds: a theoretical study

Literature Information

Publication Date 2008-05-09
DOI 10.1039/B804662J
Impact Factor 6.222
Authors

András Stirling, Andrea Hamza, Tibor András Rokob, Imre Pápai


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Abstract

A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)3/B(C6F5)3 Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.

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