Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters

Literature Information

Publication Date 2008-04-04
DOI 10.1039/B802671H
Impact Factor 6.222
Authors

Luk Van Lokeren, Els Cartuyvels, Gregory Absillis, Rudolph Willem, Tatjana N. Parac-Vogt


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Abstract

Diffusion ordered NMR spectroscopy (DOSY NMR) is shown to be an excellent tool for observing reactive transients in the hydrolysis of the phosphatase model substrate (p-nitrophenyl)phosphate (NPP) promoted by polyoxomolybdate.

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