A new and environmentally benign precursor for the synthesis of mesoporous g-C3N4 with tunable surface area
Literature Information
Jie Xu, Hai-Tao Wu, Xiang Wang, Bing Xue, Yong-Xin Li, Yong Cao
An environmentally benign and widely available precursor, guanidinium chloride, has been employed, for the first time, for the synthesis of mesoporous g-C3N4 materials via a nanocasting method using 12 nm colloid silica as a hard template. A series of mesoporous g-C3N4 (C3N4-G-r) samples with bimodal pore systems (1.8 and 13.4 nm), and high surface areas (146–215 m2 g−1) along with large pore volumes (0.57–0.84 m3 g−1), depending on the amount of templates, have been successfully prepared. Several techniques including X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and CHN elemental analysis have confirmed the formation of graphitic structures and extremely high nitrogen content of the synthesized C3N4-G-r materials. In Friedel–Crafts acylation reaction between hexanoyl chloride and benzene, C3N4-G-r samples, especially C3N4-G-1.0 with a large surface area of 215 m2 g−1, have demonstrated high catalytic conversions, affording a maximum yield of 86% of n-hexanophenone in 4 h at 80 °C.
Related Literature
Validation of new microvolume Couette flow linear dichroism cells
Rachel Marrington, Timothy R. Dafforn, David J. Halsall, James I. MacDonald, Matthew Hicks, Alison Rodger
DOI: 10.1039/B506149K
Photoelectrochemical ruler: measurement at the micron scale
Nicole Fietkau, Javier del Campo, Roser Mas, Francesc Xavier Muñoz, Richard G. Compton
DOI: 10.1039/B711828G
Aggregation-induced phosphorescence of iridium(iii) complexes with 2,2′-bipyridine-acylhydrazone and their highly selective recognition to Cu2+
Na Zhao, Yu-Hui Wu, Jian Luo, Lin-Xi Shi
DOI: 10.1039/C2AN36501D
Combination of FTIRspectral imaging and chemometrics for tumour detection from paraffin-embedded biopsies
Elodie Ly, Olivier Piot, Rolf Wolthuis, Anne Durlach, Philipe Bernard, Michel Manfait
DOI: 10.1039/B715924B
Angular-dependent metal-enhanced fluorescence from silver colloid-deposited films: opportunity for angular-ratiometric surface assays‡
Kadir Aslan, Stuart N. Malyn, Chris D. Geddes
DOI: 10.1039/B709170B
Sample preparation: a challenge in the development of point-of-care nucleic acid-based assays for resource-limited settings
Magda Anastassova Dineva, Lourdes Mahilum-Tapay, Helen Lee
DOI: 10.1039/B705672A
Raman spectroscopic monitoring of droplet polymerization in a microfluidic device
Susan E. Barnes, Zuzanna T. Cygan, Jesse K. Yates, Kathryn L. Beers, Eric J. Amis
DOI: 10.1039/B603693G
Electrochemical oxidation of catecholamines and catechols at carbon nanotube electrodes
Stephen Maldonado, Stephen Morin, Keith J. Stevenson
DOI: 10.1039/B506869J
Colloidal gold–polystyrene bead hybrid for chemiluminescent detection of sequence-specific DNA
Aiping Fan, Choiwan Lau, Jianzhong Lu
DOI: 10.1039/B714148C
Evaluation of bio-compatible poly(ethylene glycol)-based solid-phase microextraction fiber for in vivo pharmacokinetic studies of diazepam in dogs
Ali Es-haghi, Xu Zhang, Florin Marcel Musteata, Habib Bagheri, Janusz Pawliszyn
DOI: 10.1039/B701423F
You might also like
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![(2S)-2-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-4-pentynoic acid structure (2S)-2-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-4-pentynoic acid structure](https://static.chemtradehub.com/structs/630/63039-48-5-b66d.webp)


![10-(1-Azabicyclo[2.2.2]oct-3-ylmethyl)-10H-phenothiazine structure 10-(1-Azabicyclo[2.2.2]oct-3-ylmethyl)-10H-phenothiazine structure](https://static.chemtradehub.com/structs/292/29216-28-2-1d81.webp)
