A three-dimensional lanthanide-organic radical open-framework
Literature Information
Nans Roques, Daniel Maspoch, Inhar Imaz, Angela Datcu, Jean-Pascal Sutter, Concepció Rovira, Jaume Veciana
The reaction of a 3-connecting PTMTC radical with Tb(III) ions forms a three-dimensional open-framework with the formula [Tb(PTMTC)(DMF)3] (1), which associates a lattice complex T topology with large channels, guest-induced reversible crystal to amorphous transformations and ferromagnetic metal-radical interactions.
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