Clean and efficient synthesis of O-silylcarbamates and ureas in supercritical carbon dioxide
Literature Information
Matthew J. Fuchter, Catherine J. Smith, Alistair Boyer, Simon Saubern, John H. Ryan, Andrew B. Holmes
The synthesis of a family of O-silylcarbamates from the corresponding silylamines has been achieved simply by heating the silylamine in supercritical carbon dioxide (scCO2), and these O-silylcarbamates have been shown to be effective precursors for the synthesis of a range of symmetrical and unsymmetrical ureas.
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