Selective oxidation of dimethyl ether to methyl formate over trifunctional MoO3–SnO2catalyst under mild conditions

Literature Information

Publication Date 2013-03-19
DOI 10.1039/C3GC40279G
Impact Factor 10.182
Authors

Qingde Zhang, Yizhuo Han, Yisheng Tan


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Abstract

Dimethyl ether oxidation was conducted over MoO3–SnO2 catalysts prepared from different Sn salt precursors. Over the MoO3–SnO2 catalyst prepared from SnCl4, methyl formate selectivity reached 94.1% at 433 K without the formation of COx. The performance of the catalyst was determined by the existence form of MoO3 and the different surface bonding of Mo and O of the catalyst.

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