Ionic liquid forms of the herbicide dicamba with increased efficacy and reduced volatility

Literature Information

Publication Date 2013-06-03
DOI 10.1039/C3GC37143C
Impact Factor 10.182
Authors

O. Andreea Cojocaru, Julia L. Shamshina, Gabriela Gurau, Anna Syguda, Tadeusz Praczyk, Juliusz Pernak, Robin D. Rogers


View Original

Abstract

Twenty eight new dicamba (3,6-dichloro-2-methoxybenzoic acid)-based herbicidal salts, have been synthesized and characterized in order to attempt to improve the efficacy of this widely known herbicide used to protect maize, grassland, and other cultures. The new compounds, most of which are ionic liquids by definition and three of which are solids melting above 100 °C, were prepared by pairing quaternary tetraalkyl- or alkoxyammonium, piperidinium, imidazolium, pyridinium, morpholinium, quinolinium, and phosphonium cations with the dicamba anion. Growth chamber and field test data suggested that ionic liquid forms of dicamba offer substantially increased efficacy which would allow less to be applied in the field. Compared to the commercial dicamba free acid product, improved physical properties were observed including higher decomposition temperatures and reduced volatilities, suggesting a potential reduction of overall environmental impact of this herbicide.

Related Literature

Synthesis, characterization and crystal structures of novel fluorinated di(thiazolyl)benzene derivatives

Maciej Barłóg, Ihor Kulai, Xiaozhou Ji, Nattamai Bhuvanesh, Somnath Dey, Eric Pierre Sliwinski, Hassan S. Bazzi, Lei Fang, Mohammed Al-Hashimi

2019-02-07 Research Article

DOI: 10.1039/C9QO00044E

Copper and silver benzoate and aryl complexes and their implications for oxidative decarboxylative coupling reactions

Andreas Baur, Katelyn A. Bustin, Ellen Aguilera, Jeffrey L. Petersen, Jessica M. Hoover

2017-01-04 Research Article

DOI: 10.1039/C6QO00678G

Visible light enabled γ-trifluoromethylation of Baylis–Hillman acetates: stereoselective synthesis of trisubstituted alkenes

Arvind Kumar Yadav, Anup Kumar Sharma, Krishna Nand Singh

2019-02-14 Research Article

DOI: 10.1039/C9QO00166B

Asymmetric hydrogenation of α-hydroxy ketones with an iridium/f-amphox catalyst: efficient access to chiral 1,2-diols

Weilong Wu, Yun Xie, Pan Li, Xiuxiu Li, Yuanhua Liu, Xiu-Qin Dong

2017-01-09 Research Article

DOI: 10.1039/C6QO00810K

Polycyclic heteroaromatic hydrocarbons containing a benzoisoindole core

Marcus Richter, Karl Sebastian Schellhammer, Peter Machata, Gianaurelio Cuniberti, Alexey Popov, Frank Ortmann, Reinhard Berger, Klaus Müllen, Xinliang Feng

2017-04-04 Research Article

DOI: 10.1039/C7QO00180K

The impact of interplay between electronic and steric effects on the synthesis and the linear and non-linear optical properties of diketopyrrolopyrrole bearing benzofuran moieties

Anna Purc, Beata Koszarna, Irina Iachina, Daniel H. Friese, Mariusz Tasior, Krzysztof Sobczyk, Tomasz Pędziński, Jonathan Brewer, Daniel T. Gryko

2017-02-07 Research Article

DOI: 10.1039/C6QO00869K

1,3-Dipolar cycloadditions with meso-tetraarylchlorins – site selectivity and mixed bisadducts

José Almeida, António Aguiar, Andreia Leite, André M. N. Silva, Luís Cunha-Silva, Baltazar de Castro, Maria Rangel, Giampaolo Barone, Augusto C. Tomé, Ana M. G. Silva

2017-01-10 Research Article

DOI: 10.1039/C6QO00771F

The synthesis, structure, and properties of 5,6,11,12-tetraarylindeno[1,2-b]fluorenes and their applications as donors for organic photovoltaic devices

Yuan-Chih Lo, Hao-Chun Ting, Ya-Ze Li, Yi-Hua Li, Shun-Wei Liu, Kuo-Wei Huang

2016-12-01 Research Article

DOI: 10.1039/C6QO00673F

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Green Chemistry

Green Chemistry
CiteScore: 16.1
Self-citation Rate: 7.5%
Articles per Year: 944

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.