Construction of C1-symmetric zirconium complexes by the design of new Salan ligands. Coordination chemistry and preliminary polymerisation catalysis studies
Literature Information
Ad Cohen, Adi Yeori, Jacob Kopilov, Israel Goldberg, Moshe Kol
The first synthesis of achiral and chiral [ONNO′]-type Salan ligands featuring two different phenol arms, and the diastereoselective formation of the corresponding octahedral C1-symmetric zirconium complexes is described; the activity and isospecificity induction of the [ONNO′]Zr(bn)2 complexes in 1-hexene polymerisation reflected those of the parent symmetric compounds.
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