Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane

Literature Information

Publication Date 2008-03-03
DOI 10.1039/B718813G
Impact Factor 6.222
Authors

Yasuo Norikane, Ryuzi Katoh, Nobuyuki Tamaoki


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Abstract

Sterically hindered [0.0](3,3′)-azobenzenophane exhibits thermal trans-to-cisisomerization to the thermodynamically stable cis–cis isomer, and reversible photochemical isomerization with good fatigue resistance.

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