Unconventional thermodynamically stable cis isomer and trans to cis thermal isomerization in reversibly photoresponsive [0.0](3,3′)-azobenzenophane
Literature Information
Yasuo Norikane, Ryuzi Katoh, Nobuyuki Tamaoki
Sterically hindered [0.0](3,3′)-azobenzenophane exhibits thermal trans-to-cisisomerization to the thermodynamically stable cis–cis isomer, and reversible photochemical isomerization with good fatigue resistance.
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![(4aR,5S,6R,8aS)-5-[2-(3-Furyl)ethyl]-8a-(hydroxymethyl)-5,6-dimethyl-3,4,4a,5,6,7,8,8a-octahydro-1-naphthalenecarboxylic acid structure (4aR,5S,6R,8aS)-5-[2-(3-Furyl)ethyl]-8a-(hydroxymethyl)-5,6-dimethyl-3,4,4a,5,6,7,8,8a-octahydro-1-naphthalenecarboxylic acid structure](https://static.chemtradehub.com/structs/184/18411-75-1-d4cd.webp)
