Univalent transition metal complexes of arenes stabilized by a bulky terphenylligand: differences in the stability of Cr(i), Mn(i) or Fe(i) complexes

Literature Information

Publication Date 2007-12-20
DOI 10.1039/B715027J
Impact Factor 6.222
Authors

Chengbao Ni, Bobby D. Ellis, James C. Fettinger, Gary J. Long, Philip P. Power


View Original

Abstract

Two univalent transition metal complexes, (µ-η6:η6-C7H8){MnAr*-3,5-Pri2}2 (1) and (η6-C6H6)FeAr*-3,5-Pri2 (2) (Ar*-3,5-Pri2 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2), that have η6 arene coordination were synthesized by reduction of the corresponding metal halides. The complexes are thermally stable in contrast to the corresponding Cr(I) complexes of benzene or toluene which decompose at room temperature.

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