Stepwise formation of “organometallic boxes” with half-sandwich Ir, Rh and Ru fragments

Literature Information

Publication Date 2007-10-31
DOI 10.1039/B711809K
Impact Factor 6.222
Authors

Ying-Feng Han, Yue-Jian Lin, Lin-Hong Weng, Guo-Xin Jin


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Abstract

Octanuclear complexes with half-sandwich Ir, Rh and Ru fragments and tetra(4-pyridyl)porphyrin (L1) and oxalate (L2) spacer ligands [(Cp*M)4L1]2[L2]4 (M = Ir (6a) M = Rh (6b)), [((cymene)Ru)4(L1)]2[L2]4 were prepared and characterized.

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