Using ionic liquids to trap unique coordination environments: polymorphic solvates of ErCl3(OH2)4·2([C2mim]Cl)

Literature Information

Publication Date 2007-10-29
DOI 10.1039/B711679A
Impact Factor 6.222
Authors

C. Corey Hines, Violina A. Cocalia, Robin D. Rogers


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Abstract

Two polymorphs of ErCl3(OH2)4路2([C2mim]Cl) solvates were isolated from the same solution of 1-ethyl-3-methylimidazolium chloride when HCl(aq) was added, while [C2mim]3[ErCl6] was isolated without HCl addition, illustrating how ionic liquids can be used to trap unusual coordination environments in the solid state.

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