Using ionic liquids to trap unique coordination environments: polymorphic solvates of ErCl3(OH2)4·2([C2mim]Cl)
Literature Information
C. Corey Hines, Violina A. Cocalia, Robin D. Rogers
Two polymorphs of ErCl3(OH2)4路2([C2mim]Cl) solvates were isolated from the same solution of 1-ethyl-3-methylimidazolium chloride when HCl(aq) was added, while [C2mim]3[ErCl6] was isolated without HCl addition, illustrating how ionic liquids can be used to trap unusual coordination environments in the solid state.
Related Literature
D3h CN3Be3+ and CO3Li3+: viable planar hexacoordinate carbon prototypes
Yan-Bo Wu, Yan Duan, Gang Lu, Hai-Gang Lu, Pin Yang, Paul von Ragué Schleyer, Gabriel Merino, Zhi-Xiang Wang
DOI: 10.1039/C2CP41822C
The invalidity of the photo-induced electron transfer mechanism for fluorescein derivatives
Panwang Zhou, Jianyong Liu, Songqiu Yang, Junsheng Chen, Keli Han, Guozhong He
DOI: 10.1039/C2CP42167D
Effect of heavy water on phospholipid membranes: experimental confirmation of molecular dynamics simulations
Lenka Beranová, Jana Humpolíčková, Jan Sýkora, Aleš Benda, Lukasz Cwiklik, Piotr Jurkiewicz, Gerhard Gröbner, Martin Hof
DOI: 10.1039/C2CP41275F
Quantum dynamics study of the Cl + CH4 → HCl + CH3 reaction: reactive resonance, vibrational excitation reactivity, and rate constants
Fanbin Meng, Wei Yan, Dunyou Wang
DOI: 10.1039/C2CP41917C
Kinetics and mechanism of the reaction of OH with the trimethylbenzenes – experimental evidence for the formation of adduct isomers
Birger Bohn
DOI: 10.1039/C2CP42434G
Double-chain planar D2h B4H2, C2h B8H2, and C2h B12H2: conjugated aromatic borenes
Yan-Bo Wu, Hai-Gang Lu
DOI: 10.1039/C2CP40902J
Water structure and charge transfer phenomena at the liquid–graphene interface
Luisa D'Urso, Cristina Satriano, Giuseppe Forte, Giuseppe Compagnini, Orazio Puglisi
DOI: 10.1039/C2CP42249B
Transient IR spectroscopy and ab initio calculations on ESIPT in 3-hydroxyflavone solvated in acetonitrile
Katharina Chevalier, Matthias M. N. Wolf, Andreas Funk, Marko Andres, Markus Gerhards, Rolf Diller
DOI: 10.1039/C2CP41077J
Surface orientation effects in crystalline–amorphous silicon interfaces
Michael Nolan, Merid Legesse, Giorgos Fagas
DOI: 10.1039/C2CP42679J
Geometrical requirements for transition-metal-centered aromatic boron wheels: the case of VB10−
Wei-Li Li, Constantin Romanescu, Zachary A. Piazza, Lai-Sheng Wang
DOI: 10.1039/C2CP42218B
You might also like
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry










![[3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol structure [3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol structure](https://static.chemtradehub.com/structs/278/278597-30-1-5c79.webp)


![6,7-Dihydro-5H-pyrrolo[1,2-a]imidazole-6-carboxylic acid structure 6,7-Dihydro-5H-pyrrolo[1,2-a]imidazole-6-carboxylic acid structure](https://static.chemtradehub.com/structs/136/1369160-12-2-6524.webp)
