One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence

Literature Information

Publication Date 2007-08-07
DOI 10.1039/B709754A
Impact Factor 6.222
Authors

Daniel L. Comins, Jason M. Dinsmore, Lucas R. Marks


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Abstract

A one-carbon homologation of terminal alkenes has been developed utilizing an olefin cross-metathesis followed by a palladium-mediated allylic carbonate reduction; various substrates were used to demonstrate the scope of the reaction, with yields ranging from 65 to 86%.

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