Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides‡

Literature Information

Publication Date 2007-06-21
DOI 10.1039/B705284G
Impact Factor 6.222
Authors

Jean-Philippe Goddard, Catherine Gomez, Franck Brebion, Sophie Beauvière, Louis Fensterbank, Max Malacria


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Abstract

SET oxidation of bis-sulfinyl anions has enabled the uses of bis-sulfinyl radical as a synthetic equivalent of chiral acyl and methylene radicals involved in tandem reactions leading to the enantioselective construction of various carbo- and heterocyclic derivatives.

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