Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides‡
Literature Information
Jean-Philippe Goddard, Catherine Gomez, Franck Brebion, Sophie Beauvière, Louis Fensterbank, Max Malacria
SET oxidation of bis-sulfinyl anions has enabled the uses of bis-sulfinyl radical as a synthetic equivalent of chiral acyl and methylene radicals involved in tandem reactions leading to the enantioselective construction of various carbo- and heterocyclic derivatives.
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