Palladium–NHC complexes do catalyse the diboration of alkenes: mechanistic insights
Literature Information
Publication Date
2007-06-12
DOI
10.1039/B705197B
Impact Factor
6.222
Authors
Vanesa Lillo, Elena Mas-Marzá, Anna M. Segarra, Jorge J. Carbó, Eduardo Peris, Elena Fernandez
View Original
Abstract
Novel catalytic activation of the B–B bond by palladium(II)–NHC complexes in presence of a mild base (NaOAc) and an excess of diboron reagent enables chemoselective 1,2-diboration of alkenes, suggesting the heterolytic cleavage of diboron rather than oxidative addition of a B–B bond to the metal.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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Recommended Compounds
![2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure](https://static.chemtradehub.com/structs/308/3089-17-6-750b.webp "2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure")
2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione
CAS Number:
3089-17-6
Molecular Formula:
C20H10Cl2N2O2
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