Two-dimensional hopping motion of encapsulated La atoms in silylated La2@C80
Literature Information
Takatsugu Wakahara, Michio Yamada, Satomi Takahashi, Tsukasa Nakahodo, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Masahiro Kako, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Shigeru Nagase
The 139La NMR study of the exohedrally functionalized derivatives of La2@C80 metallofullerene, La2@C80(Ar2Si)2CH2 (3a: Ar = Mes, Mes = mesityl, 3b: Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C80 cage.
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