Two-dimensional hopping motion of encapsulated La atoms in silylated La2@C80

Literature Information

Publication Date 2007-04-12
DOI 10.1039/B703473C
Impact Factor 6.222
Authors

Takatsugu Wakahara, Michio Yamada, Satomi Takahashi, Tsukasa Nakahodo, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Masahiro Kako, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Shigeru Nagase


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Abstract

The 139La NMR study of the exohedrally functionalized derivatives of La2@C80 metallofullerene, La2@C80(Ar2Si)2CH2 (3a: Ar = Mes, Mes = mesityl, 3b: Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C80 cage.

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