Efficient stabilization of copper(iii) in tetraaza pseudo-macrocyclic oxime-and-hydrazideligands with adjustable cavity size
Literature Information
Igor O. Fritsky, Henryk Kozłowski, Olga M. Kanderal, Matti Haukka, Jolanta Świątek-Kozłowska, Elżbieta Gumienna-Kontecka, Franc Meyer
Substitution of the amide donors in open-chain {2N(oxime), 2N(amide)} ligands by hydrazide donors gives new pseudo-macrocyclic copper complexes that show a significant decrease of the Cu3+/2+ redox potentials in both mono- and polynuclear systems, thus demonstrating a pronounced capacity of such ligand systems to efficiently stabilize the trivalent copper.
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