Efficient stabilization of copper(iii) in tetraaza pseudo-macrocyclic oxime-and-hydrazideligands with adjustable cavity size

Literature Information

Publication Date 2006-08-22
DOI 10.1039/B608236J
Impact Factor 6.222
Authors

Igor O. Fritsky, Henryk Kozłowski, Olga M. Kanderal, Matti Haukka, Jolanta Świątek-Kozłowska, Elżbieta Gumienna-Kontecka, Franc Meyer


View Original

Abstract

Substitution of the amide donors in open-chain {2N(oxime), 2N(amide)} ligands by hydrazide donors gives new pseudo-macrocyclic copper complexes that show a significant decrease of the Cu3+/2+ redox potentials in both mono- and polynuclear systems, thus demonstrating a pronounced capacity of such ligand systems to efficiently stabilize the trivalent copper.

Related Literature

Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki coupling

Jun Terao, Andrew Tang, Jasper J. Michels, Alexander Krivokapic, Harry L. Anderson

2003-11-27 Communication

DOI: 10.1039/B311762F

Unexpected cleavage of tetrahydrofuran by catalytic reductive lithiation

Stéphane Streiff, Nigel Ribeiro, Laurent Désaubry

2004-01-13 Communication

DOI: 10.1039/B312972A

Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex

Makoto Minato, Takaomi Matsumoto, Miyuki Ichikawa, Takashi Ito

2003-11-03 Communication

DOI: 10.1039/B310663M

Multiple active oxidants in competitive epoxidations catalyzed by porphyrins and corroles

James P. Collman, Li Zeng, Richard A. Decréau

2003-11-03 Communication

DOI: 10.1039/B310763A

Encapsulation of paramagnetic 3d1-vanadium(iv) in an antiferromagnetically coupled dodecanuclear copper(ii) cage

Arindam Mukherjee, Munirathinam Nethaji, Akhil R. Chakravarty

2003-11-04 Communication

DOI: 10.1039/B310521K

Nucleic acid binding properties of thyminyl and adeninyl pyrrolidine-amideoligonucleotide mimics (POM)

T. H. Samuel Tan, David T. Hickman, Jordi Morral, Ian G. Beadham, Jason Micklefield

2004-01-28 Communication

DOI: 10.1039/B315768G

Fabrication of two-dimensionally ordered macroporous silica materials with controllable dimensions

Mandakini Kanungo, Maryanne M. Collinson

2004-02-04 Communication

DOI: 10.1039/B311936J

Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS–HS to LS–LS transition

Ben A. Leita, Boujemaa Moubaraki, Keith S. Murray, Jonathan P. Smith, John D. Cashion

2003-11-20 Communication

DOI: 10.1039/B311818E

Noncontact two-color luminescence thermometry based on intramolecular luminophore cyclization within an ionic liquid

Gary A. Baker, Sheila N. Baker, T. Mark McCleskey

2003-10-30 Communication

DOI: 10.1039/B310459C

Self-indicating amine scavenger resins

Jin Ku Cho, Peter D. White, Wolfgang Klute, Tony W. Dean, Mark Bradley

2004-01-27 Communication

DOI: 10.1039/B315426B

You might also like

Compound Q&A

How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?

Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...

88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A

What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?

Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...

1385031-14-0Triethoxy(octyl)sila...
Compound Q&A

Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?

Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...

864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A

Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?

Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...

266317-71-9Benzene, bis[(trimet...
Compound Q&A

Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?

Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...

1452-17-1Isothiazole-3-carbon...
Compound Q&A

Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?

(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...

873-63-2(3-Chlorophenyl)meth...
Compound Q&A

How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?

(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...

959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A

What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?

Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...

788081-99-2Methyl 2-(bromomethy...
Compound Q&A

What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?

6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...

904805-36-36,8-Dibromoimidazo[1...
Compound Q&A

Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?

3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...

573675-27-13-Amino-5-bromo-2-py...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.