Unexpected cleavage of tetrahydrofuran by catalytic reductive lithiation
Literature Information
Stéphane Streiff, Nigel Ribeiro, Laurent Désaubry
DBB, an electron transporter, can open THF at room temperature under sonication without any Lewis acid activation. This feature was successfully exploited in the straightforward synthesis of bis-silanes.
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![9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate structure 9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate structure](https://static.chemtradehub.com/structs/131/1314378-14-7-4316.webp)
