Unexpected cleavage of tetrahydrofuran by catalytic reductive lithiation

Literature Information

Publication Date 2004-01-13
DOI 10.1039/B312972A
Impact Factor 6.222
Authors

Stéphane Streiff, Nigel Ribeiro, Laurent Désaubry


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Abstract

DBB, an electron transporter, can open THF at room temperature under sonication without any Lewis acid activation. This feature was successfully exploited in the straightforward synthesis of bis-silanes.

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