Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions
Literature Information
Esther Quintanilla, Fabio di Lena, Peter Chen
Chemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-catalyzed polymerization of ethylene identify the two observed chain-bearing species to be alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed mechanism.
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