Switching a molecular shuttle on and off: simple, pH-controlled pseudorotaxanes based on cucurbit[7]uril

Literature Information

Publication Date 2006-03-31
DOI 10.1039/B601959E
Impact Factor 6.222
Authors

Vladimir Sindelar, Serena Silvi, Angel E. Kaifer


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Abstract

Cucurbit[7[uril, the wheel component in two new and structurally simple pseudorotaxanes, shuttles between the two axle termini at low pH, whereas the shuttling motion stops at higher pH, as the wheel is bound to the center of the axle.

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