Recent advances in the development of rotaxanes and pseudorotaxanes based on pillar[n]arenes: from construction to application
Literature Information
Publication Date
2019-10-07
DOI
10.1039/C9CC07373F
Impact Factor
6.222
Authors
Kui Yang, Shuang Chao, Feiyu Zhang, Yuxin Pei, Zhichao Pei
View Original
Abstract
Mechanically inter-locked molecules (MIMs) mainly including rotaxanes and pseudorotaxanes have attracted enormous attention for the fabrication of molecular machines, which can be constructed from macrocyclic molecules as the main building blocks through host–guest complexation. Pillar[n]arenes, as a new class of macrocyclic molecules, have a rigid pillar-like shaped architecture with an electron-rich cavity and two fine-tuneable rims. This unique symmetrical and rigid structure, easy modification and excellent properties in host–guest complexation provides pillar[n]arenes with the ability to form various interesting supramolecular systems. Importantly, the π-rich cavity of pillar[n]arenes also endows them with the ability to construct MIMs. This article will provide a comprehensive review of recent advances in pillar[n]arene-based MIMs, primarily focusing on rotaxanes and pseudorotaxanes, and their synthetic methods will be highlighted. In addition, the applications of pillar[n]arene-based MIMs will be summarized while current limitations and perspectives on the construction of pillar[n]arene-based MIMs will also be outlined.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure](https://static.chemtradehub.com/structs/761/761423-87-4-dbeb.webp "(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure")
(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol
CAS Number:
761423-87-4
Molecular Formula:
C21H21FO5S
Trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
CAS Number:
78560-45-9
Molecular Formula:
C8H4Cl3F13Si
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