A fully self-assembled non-symmetric triad for photoinduced charge separation
Literature Information
Publication Date
2010-12-24
DOI
10.1039/C0SC00520G
Impact Factor
9.825
Authors
G. Dan Pantoş, Jeremy K. M. Sanders, Michele Orlandi, Claudio Chiorboli, Sandro Fracasso
View Original
Abstract
A very efficient and successful metal-mediated strategy towards the formation of a non-symmetric triad is described: appropriate Lewis acid and/or base functions on the molecular components (a naphthalenediimide, an aluminium(III) porphyrin, and a ruthenium(II) porphyrin) lead to the desired product uniquely. The photophysics of the triad was investigated in detail using time-resolved spectroscopy in the pico- and nanosecond time domains. The strategy is of great potential interest as, while confining the synthetic effort to the single components, it can give access to a wide range of photoactive systems.
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Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
Articles per Year:
1413
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