Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes: formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2-P(NiPr2)NR}] and diazoalkane insertions into metal–phosphorus bonds

Literature Information

Publication Date 2005-07-29
DOI 10.1039/B505472A
Impact Factor 6.222
Authors

Konstantin A. Udachin


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Abstract

The bridging phosphinidene complexes [Mn2(CO)8(μ-PNiPr2)] and [Co2(CO)4(μ-dppm)( μ-PNR2)] (NR2 = NiPr2, TMP) react with heterocumulenes RN3, CH2N2 and Ph2CNN to form complexes with μ-η1,η2-aminophosphaimine, μ-η1,η2-aminophosphaalkene and μ-η1,η2-aminophosphadiphenylmethylazaimine ligands, respectively.

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