Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

Literature Information

Publication Date 2005-07-06
DOI 10.1039/B502568K
Impact Factor 6.222
Authors

Yun Liu, Xabier Lopez, Darrin M. York


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Abstract

Primary and secondary kinetic and equilibrium isotope effects are calculated with density-functional methods for the dianionic methanolysis of the native (unsubstituted) and thio-substituted ethylene phosphates.

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