Tetraalkynyl calix[4]arenes with advanced NLO properties
Literature Information
Gunther Hennrich, M. Teresa Murillo, Pilar Prados, Kai Song, Inge Asselberghs, Koen Clays, André Persoons, Jordi Benet-Buchholz, Javier de Mendoza
Rigid, highly conjugated tetraalkynyl-calix[4]arenes synthesised via Sonogashira coupling give rise to improved second-order hyperpolarizability values as determined by hyper-Rayleigh scattering—a technique that in addition to X-ray crystallography also allows for the conformational analysis of the calixarene structures in solution.
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