![(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone structure](https://static.chemtradehub.com/structs/102/102271-49-8-cba7.webp "(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone structure")
(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone
CAS Number:
102271-49-8
Molecular Formula:
C19H26O3
Diastereoselective metal-catalyzed [4 + 2 + 2] carbocyclization reactions utilizing a rhodium N-heterocyclic carbene (NHC) complex: the first example of a rhodium NHC-catalyzed [m + n + o] carbocyclization
Literature Information
Publication Date
2004-11-19
DOI
10.1039/B413438A
Impact Factor
6.222
Authors
P. Andrew Evans, Erich W. Baum, Aleem N. Fazal, Maren Pink
View Original
Abstract
The air and moisture stable rhodium N-heterocyclic carbene (NHC) complex, RhCl(IMes)(COD) (IMes = N,N′-bis(2,4,6-trimethylphenyl)imidazole-2-ylidine; COD = 1,5-cyclooctadiene), facilitates a diastereoselective metal-catalyzed [4 + 2 + 2] carbocyclization of 1,6-enynes in the presence of silver triflate and 1,3-butadiene.
Recommended Journals
Related Literature
Electronic structure of Lewis acid sites on high surface area aluminium fluorides: a combined XPS and ab initio investigation
Christine L. Bailey, Erhard Kemnitz, Sanghamitra Mukhopadhyay, Adrian Wander, Barry G. Searle
2009-05-08
Paper
DOI: 10.1039/B821484K
Model non-equilibrium molecular dynamics simulations of heat transfer from a hot gold surface to an alkylthiolate self-assembled monolayer
Yue Zhang, George L. Barnes, Tianying Yan, William L. Hase
2010-02-24
Paper
DOI: 10.1039/B923858C
The photoionisation of two phenylcarbenes and their diazirine precursors investigated using synchrotron radiation
Bastian Noller, Patrick Hemberger, Ingo Fischer, Christian Alcaraz, Gustavo A. Garcia, Héloïse Soldi-Lose
2009-04-22
Paper
DOI: 10.1039/B823269E
DFT 2H quadrupolar coupling constants of ruthenium complexes: a good probe of the coordination of hydrides in conjuction with experiments
Iker del Rosal, Torsten Gutmann, Laurent Maron, Franck Jolibois, Bruno Chaudret, Bernadeta Walaszek, Hans-Heinrich Limbach, Romuald Poteau, Gerd Buntkowsky
2009-05-05
Paper
DOI: 10.1039/B822150B
Preparation, structure, and stability of Pt and Pd monolayer modified Pd and Pt electrocatalysts
P. P. Wells, E. M. Crabb, C. R. King, R. Wiltshire, B. Billsborrow, D. Thompsett, A. E. Russell
2009-05-12
Paper
DOI: 10.1039/B823504J
A wavepacket study of the low-energy charge transfer process in the S3+ + H reaction using time-resolved electronic densities
Marta Łabuda, Jesús González-Vázquez, Leticia González
2010-04-08
Paper
DOI: 10.1039/B926825A
Initiated and oxidative chemical vapor deposition: a scalable method for conformal and functional polymer films on real substrates
Salmaan H. Baxamusa, Sung Gap Im, Karen K. Gleason
2009-03-26
Perspective
DOI: 10.1039/B900455F
An embedded cluster study of the formation of water on interstellar dust grains
T. P. M. Goumans, C. Richard A. Catlow, Wendy A. Brown, Johannes Kästner, Paul Sherwood
2009-04-23
Paper
DOI: 10.1039/B816905E
Ellipsometric study of the displacement of milk proteins from the oil–water interface by the non-ionic surfactant C10E8
James P. R. Day, Paul D. A. Pudney, Colin D. Bain
2010-03-16
Paper
DOI: 10.1039/B921887D
Theoretical evaluation of zeolite confinement effects on the reactivity of bulky intermediates‡
David Lesthaeghe, Veronique Van Speybroeck, Michel Waroquier
2009-05-14
Perspective
DOI: 10.1039/B902364J
You might also like
Compound Q&A
What are the main uses of (3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8)?
(3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8) is primari...
79066-03-8(3.beta.)-3-Hydroxy-...
Compound Q&A
What regulatory guidelines apply to 5-(aminomethyl)-2-methoxyphenol (CAS: 89702-89-6)?
5-(Aminomethyl)-2-methoxyphenol (CAS: 89702-89-6) is classified under GHS as a s...
89702-89-65-(aminomethyl)-2-me...
Compound Q&A
What is Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7)?
Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7) is a heterocyclic organic compo...
28981-13-7Thieno[2,3-c]pyridin...
Compound Q&A
Is 1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride (CAS: 1185311-28-7) safe?
1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride is generally ...
1185311-28-71-[(6-Methoxy-3-pyri...
Compound Q&A
What regulatory guidelines apply to [(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2)?
[(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2) is regulated und...
146404-58-2[(2E)-3-Phenyl-2-pro...
Compound Q&A
What regulatory guidelines apply to 6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7)?
6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7) falls under the scope of the Glob...
1620515-86-76-Bromo-7-methoxyqui...
Compound Q&A
What industries use (2R)-1-(1-Benzofuran-2-yl)-N-propyl-2-pentanamine (CAS: 260550-89-8)?
This compound is primarily used in the pharmaceutical industry for the developme...
260550-89-8(2R)-1-(1-Benzofuran...
Compound Q&A
What are the main uses of 1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2,3-b]pyrazin-2(1H)-one (CAS: 1228013-15-7)?
1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2...
1228013-15-71-Ethyl-7-[2-methyl-...
Compound Q&A
Are there alternatives to {5-(Acryloylamino)-2-[(dimethylamino)methyl]phenyl}boronic acid (CAS: 1217500-78-1) in synthesis?
Alternative reagents such as 2-[(dimethylamino)methyl]phenylboronic acid or rela...
1217500-78-1{5-(Acryloylamino)-2...
Compound Q&A
What is 3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2)?
3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2) is an organic compound with the...
310881-48-23-(Piperidin-4-yloxy...
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![N-[(6-Bromo-3-pyridinyl)methyl]ethanamine structure](https://static.chemtradehub.com/structs/120/120740-05-8-ca55.webp "N-[(6-Bromo-3-pyridinyl)methyl]ethanamine structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.