Synthesis and structural characterization of highly chlorinated C70, C70Cl28

Literature Information

Publication Date 2004-11-19
DOI 10.1039/B412448K
Impact Factor 6.222
Authors

Sergey I. Troyanov, Natalia B. Shustova, Ilya N. Ioffe, Andrew P. Turnbull, Erhard Kemnitz


View Original

Abstract

Chlorination of [70]fullerene with SbCl5, VCl4 or PCl5 yielded C70Cl28 comprising three isomers, all containing four isolated benzenoid rings in the fullerene cage. This demonstrates, for the first time for C70 derivatives, a stabilization effect due to planar aromaticity.

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