Photolysis in aqueous aerosols: 300 nm yields of Fe2+ from a ferrioxalate actinometer and of OH radical from nitrate ions

Literature Information

Publication Date 2009-04-24
DOI 10.1039/B903329G
Impact Factor 3.676
Authors

David L. Bones, Leon F. Phillips


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Abstract

300 nm photolysis yields of Fe2+ from potassium ferrioxalate and of OH from nitrate ion have been measured in aqueous aerosols, the yield from ferrioxalate in a bulk solution being used to measure the light intensity. Mie theory was used to calculate effective cross-sections for absorption and scattering of light by the aerosol droplets. Yields of OH from nitrate ion have been measured with benzoic acid and carbon monoxide radical scavengers. The photolysis yield of Fe2+ from ferrioxalate was found to be enhanced in the aerosol by a factor of 48 ± 17. This enhancement is believed to be real, and is attributed to surfactant behaviour that results in the presence of a high concentration of ferrioxalate in a region of high light intensity near the droplet surface. The experiments with benzoic acid indicate that the yield of OH from nitrate in aerosol droplets is not significantly different from the yield in bulk solution. The CO experiments appear to indicate that the total OH production in the aerosol is enhanced over that in bulk solution by a factor of 10 ± 3, but this number is not considered reliable.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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