Coordination of pertechnetate [TcO4]− to actinides

Literature Information

Publication Date 2004-09-06
DOI 10.1039/B404424J
Impact Factor 6.222
Authors

Mark J. Sarsfield, Andrew D. Sutton, Iain May, Gordon H. John, Clint Sharrad, Madeleine Helliwell


View Original

Abstract

The ability of [TcO4]− to coordinate directly to tetra- and hexa-valent actinides in the presence of organic PO ligands is confirmed in the crystallographically characterised complexes [UO2(TcO4)2(Ph3PO)3] (1) and [Th(TcO4)4(nBu3PO)4] (2).

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