Reduction of nitroaromatics to arylnitrenium ions by vinyl halide cations
Literature Information
Hao Chen, Xubin Zheng, Pengxiang Yang, R. Graham Cooks
The title reduction of nitroaromatics ArNO2 by vinyl halide radical cations CH2CH–X+˙ (X = Cl or Br) to form arylnitrenium ions ArNH+ involves a change in oxidation number of nitrogen from +3 to −1. This novel reaction provides a new route for the generation of arylnitrenium ions, a highly selective method for the detection of explosives in mixtures, and offers clues to the carcinogenic activity of nitroaromatics in vivo.
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