On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect
Literature Information
Jonathan M. Stoddard, Kenneth J. Shea
Dimethylsulfoxonium methylide reacts with dicyclohexyl(α-thiophenylmethyl)methylborane via 1,2-alkyl migration and alkyldithiaborolane via 1,2-sulfur migration.
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![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure (2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp)
