The fibre optic reflectometer: A new and simple probe for refractive index and phase separation measurements in gases, liquids and supercritical fluids

Literature Information

Publication Date 2004-02-11
DOI 10.1039/B311207A
Impact Factor 3.676
Authors

Mikhail V. Avdeev, Aleksei N. Konovalov, Viktor. N. Bagratashvili, Vladimir K. Popov, Svetlana I. Tsypina, Maia Sokolova, Jie Ke, Martyn Poliakoff


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Abstract

A fibre optic reflectometer (FOR) has been developed to monitor refractive index (n) and density (ρ) changes in gases, liquids and supercritical fluids (SCFs). The key operating principle is the measurement of the intensity of light from a light emitting diode, LED, which is reflected from the end of a fibre immersed in the medium. The amount of reflected light depends on the difference between the refractive indices of the fibre and the medium. The refractive index of the medium is related in turn to its density. The FOR is particularly sensitive to phase separation, a key aspect of supercritical fluid systems, because of the density discontinuity which accompanies the separation. This device allows the collection of data with a high spatial (9 μm-fibre diameter) and time (∼0.02 s) resolution. The small size of the fibre optic probe means that it can be put into operating reactors and even catalyst beds. Experiments are described with pure CO2 and CHF3, and mixtures CO2 + cyclohexane and CO2 + MeOH over wide pressure and temperatures ranges. The measurements are in excellent agreement with published data for these systems.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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