Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent

Literature Information

Publication Date 2003-10-22
DOI 10.1039/B311103B
Impact Factor 6.222
Authors

Tatsuo Ishiyama, Yusuke Nobuta, John F. Hartwig, Norio Miyaura


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Abstract

Aromatic C–H borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane was catalyzed by an iridium complex generated from ½[Ir(OMe)(COD)]2 and 4,4′-di-tert-butyl-2,2′-bipyridine at room temperature in hexane and afforded the corresponding aryl- and heteroarylboronates in high yields with excellent regioselectivities.

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