Structural characterisation of the first mononuclear bismuth porphyrin

Literature Information

Publication Date 2003-09-30
DOI 10.1039/B309615G
Impact Factor 6.222
Authors

Bernard Boitrel, Zakaria Halime, Lydie Michaudet, Mohamed Lachkar, Loïc Toupet


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Abstract

A single carboxylate picket bismuth porphyrin has been characterised in the solid state as the first instance of a non-dimeric structure; the carboxylate picket, bent over the macrocycle, is coordinated to the bismuth, inducing a significant distortion of the porphyrin core.

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