Triboelectric junction: a model for dynamic metal–semiconductor contacts

Literature Information

Publication Date 2023-11-15
DOI 10.1039/D3EE02870D
Impact Factor 38.532
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Abstract

Static metal–semiconductor contacts are classified into Ohmic contacts and Schottky contacts. As for dynamic metal–semiconductor contacts, the in-depth mechanism remains to be studied. We here define a “triboelectric junction” model for analyzing dynamic metal–semiconductor contacts, where a space charge region induced by the triboelectric effect dominates the electron–hole separation process. Through theoretical analysis and experiments, we conclude that the triboelectric junction influences the electric output in two aspects: (1) the junction direction determines the output polarity; (2) the junction strength determines the output magnitude. Both the junction direction and junction strength are closely related to the electron-affinity difference between the contact metal and semiconductor.

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Source Journal

Energy & Environmental Science

Energy & Environmental Science
CiteScore: 32.34
Self-citation Rate: 3.4%
Articles per Year: 481

Energy & Environmental Science is an international journal dedicated to publishing exceptionally important and high quality, agenda-setting research tackling the key global and societal challenges of ensuring the provision of energy and protecting our environment for the future. The scope is intentionally broad and the journal recognises the complexity of issues and challenges relating to energy conversion and storage, alternative fuel technologies and environmental science. For work to be published it must be linked to the energy-environment nexus and be of significant general interest to our community-spanning readership. All scales of studies and analysis, from impactful fundamental advances, to interdisciplinary research across the (bio)chemical, (bio/geo)physical sciences and chemical engineering disciplines are welcomed. Topics include, but are not limited to, the following: Solar energy conversion and photovoltaics Solar fuels and artificial photosynthesis Fuel cells Hydrogen storage and (bio) hydrogen production Materials for energy systems Capture, storage and fate of CO2, including chemicals and fuels from CO2 Catalysis for a variety of feedstocks (for example, oil, gas, coal, biomass and synthesis gas) Biofuels and biorefineries Materials in extreme environments Environmental impacts of energy technologies Global atmospheric chemistry and climate change as related to energy systems Water-energy nexus Energy systems and networks Globally applicable principles of energy policy and techno-economics

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