Towards bulk behaviour of long hydrogenated carbon chains?

Literature Information

Publication Date 2003-09-30
DOI 10.1039/B309100G
Impact Factor 3.676
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Abstract

The dipole forbidden A 1Δu(1Σ−u) ← X 1Σ+g transitions of the linear carbon chains HC2nH (n = 3–7) were observed in the gas phase under supersonic molecular beam conditions. The absorption position was found to form a progression to lower energy with respect to chain length. This is discussed in relation to the electronic structure of long HC2nH carbon chains (n < 14) and their trend towards bulk behaviour. It is determined that chains as long as 3 nm (e.g. HC26H) are still far from exhibiting the properties of a one-dimensional crystal.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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