Towards bulk behaviour of long hydrogenated carbon chains?
Literature Information
The dipole forbidden A 1Δu(1Σ−u) ← X 1Σ+g transitions of the linear carbon chains HC2nH (n = 3–7) were observed in the gas phase under supersonic molecular beam conditions. The absorption position was found to form a progression to lower energy with respect to chain length. This is discussed in relation to the electronic structure of long HC2nH carbon chains (n < 14) and their trend towards bulk behaviour. It is determined that chains as long as 3 nm (e.g. HC26H) are still far from exhibiting the properties of a one-dimensional crystal.
Recommended Journals
Related Literature
Electron dominated thermoelectric response in MNiSn (M: Ti, Zr, Hf) half-Heusler alloys
Appala Naidu Gandi, Udo Schwingenschlögl
DOI: 10.1039/C6CP01786J
Coupled metal partitioning dynamics and toxicodynamics at biointerfaces: a theory beyond the biotic ligand model framework
DOI: 10.1039/C5CP07780J
Tuning the electronic and mechanical properties of penta-graphene via hydrogenation and fluorination
Yaguang Guo, Jie Liu
DOI: 10.1039/C6CP01092J
Fabrication of chiral networks for a tri-substituted anthraquinone derivative using molecular self-assembly
Yi Hu, Kai Miao, Bao Zha, Li Xu, Xinrui Miao, Wenli Deng
DOI: 10.1039/C6CP02070D
Optical characterizations of the surface states in hybrid lead–halide perovskites
Weiguang Kong, Tao Ding, Gang Bi, Huizhen Wu
DOI: 10.1039/C6CP00325G
Correlation of the depletion layer with the Helmholtz layer in the anatase TiO2–H2O interface via molecular dynamics simulations
Lixia Sang, Yudong Zhang, Jun Wang, Yangbo Zhao, Yi-tung Chen
DOI: 10.1039/C6CP01990K
Composition dependent reactivity of titanium oxide clusters
Yao Guo, Jian-Fu Li, Xinrui Niu, Alexis Markovits, Rui-Qin Zhang
DOI: 10.1039/C5CP07425H
Collision induced state-to-state energy transfer dynamics between the 2u (1D2) and 2g (1D2) ion-pair states of I2
Shoma Hoshino, Yukio Nakano, Mitsunori Araki, Takashi Ishiwata, Koichi Tsukiyama
DOI: 10.1039/C6CP00222F
First-principles investigations of transition-metal doped bilayer WS2
Yi Yang, Xiao-Li Fan, Rui Pan, Wen-Jun Guo
DOI: 10.1039/C6CP00701E
Tuning protein–protein interactions using cosolvents: specific effects of ionic and non-ionic additives on protein phase behavior
Jan Hansen, Florian Platten, Dana Wagner, Stefan U. Egelhaaf
DOI: 10.1039/C5CP07285A
You might also like
How should waste containing 4-Bromo-3-methyl-2-thiophenecarboxylic acid (CAS: 265652-39-9) be handled?
Waste containing 4-Bromo-3-methyl-2-thiophenecarboxylic acid (CAS: 265652-39-9) ...
What industries use (2S,5S,2'S,5'S)-1,1'-(1,2-Ethanediyl)bis(2,5-dimethylphospholane) (CAS: 136779-26-5)?
(2S,5S,2'S,5'S)-1,1'-(1,2-Ethanediyl)bis(2,5-dimethylphospholane) is primarily u...
What industries use Ethyl 2-(2-bromo-5-fluorophenyl)acetate (CAS: 1214910-61-8)?
Ethyl 2-(2-bromo-5-fluorophenyl)acetate (CAS: 1214910-61-8) is used in the pharm...
How is 4-Methyl-2-benzofuran-1,3-dione (CAS: 4792-30-7) typically synthesized?
4-Methyl-2-benzofuran-1,3-dione (CAS: 4792-30-7) can be synthesized through seve...
What industries use 4,6-Dichloroquinoline-3-carbonitrile (CAS: 936498-04-3)?
4,6-Dichloroquinoline-3-carbonitrile (CAS: 936498-04-3) is used in the pharmaceu...
What are the main uses of Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I) (CAS: 385815-83-8)?
Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I) is primarily used in or...
Is 2-Bromo-5-nitrofuran (CAS: 823-73-4) safe?
2-Bromo-5-nitrofuran (CAS: 823-73-4) is generally considered safe when handled w...
How should 5-Bromo-2,3,4-trifluorobenzoic acid (CAS: 212631-85-1) be stored?
5-Bromo-2,3,4-trifluorobenzoic acid should be stored in a cool, dry place away f...
What are the main uses of Zinc bis(aminoacetate) (CAS: 7214-08-6)?
Zinc bis(aminoacetate) (CAS: 7214-08-6) is primarily used in the pharmaceutical ...
How should Adamantan-1-ylmethanol (CAS: 770-71-8) be stored?
Adamantan-1-ylmethanol should be stored in a cool, dry, and well-ventilated plac...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![[4-(Hydroxymethyl)phenyl]acetic acid structure [4-(Hydroxymethyl)phenyl]acetic acid structure](https://static.chemtradehub.com/structs/734/73401-74-8-5a54.webp)

![(2R)-2,7,8-Trimethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-6-chromanol structure (2R)-2,7,8-Trimethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-6-chromanol structure](https://static.chemtradehub.com/structs/54-/54-28-4-155c.webp)
![N-[(9Z)-9-Octadecen-1-yl]-1,3-propanediamine structure N-[(9Z)-9-Octadecen-1-yl]-1,3-propanediamine structure](https://static.chemtradehub.com/structs/717/7173-62-8-d43e.webp)