Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural models
Literature Information
Publication Date
2003-09-15
DOI
10.1039/B308171K
Impact Factor
6.222
Authors
Paul A. Clarke, Polly L. Arnold, Martin A. Smith, Louise S. Natrajan, Claire Wilson, Chuen Chan
View Original
Abstract
Model studies are presented that suggest the mechanism of the lanthanide(III) salt catalysed mono acylation of symmetrical diols proceeds via chelation of the diol and the anhydride to the lanthanide salt, followed by an ‘intramolecular’ acyl transfer.
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Chemical Communications
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