Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N′-dioxide with metal(ii) thiocyanates: isostructurality in coordination networks bearing different mono- and di-nuclear nodes‡
Literature Information
Lin-Ping Zhang, Thomas C. W. Mak
The new flexible spacer ligand 1,3-bis(4-pyridyl)propane-N,N′-dioxide forms three classes of isomorphous compounds with metal(II) thiocyanates at controlled ligand–metal molar ratios, and its μ3-O,O,O′ mode leads to a pair of coordination networks having the same (4, 4) topological characteristics but different mono- and di-nuclear nodes.
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