Extended X-ray absorption fine structure (EXAFS) characterisation of dilute palladium homogeneous catalysts

Literature Information

Publication Date 2003-09-24
DOI 10.1039/B307535D
Impact Factor 6.222
Authors

John Evans, Mark A. Newton, Thomas Neisius, Robert P. Tooze, Richard Oldman


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Abstract

Highly dilute EXAFS characterisation for the elucidation of species involved in Heck chemistry is demonstrated; the major “monomer” species of Herrmann's acetate-bridged phosphapalladadacycle is characterised and species present during the course of a 50 ppm [Pd] Pd(OAc)2/PBut3 catalysed Heck reaction are presented.

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DOI: 10.1039/C4CP90155J

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