Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

Literature Information

Publication Date 2003-09-25
DOI 10.1039/B306246E
Impact Factor 6.222
Authors

Mònica Soler, Wolfgang Wernsdorfer, Ziming Sun, John C. Huffman, David N. Hendrickson, George Christou


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Abstract

Faster- and slower-relaxing versions of the title Mn12 compound have been obtained in pure forms that crystallize in the same space group and differ only in the identity of one lattice solvent molecule; solvent loss causes isomerization from the faster- to the slower-relaxing form.

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